Relationship between Molecular Properties and Conformation of Chiral Alkanes

U Azzena, PL Luisi, UW Suter…

文献索引：Azzena, Ugo; Luisi, Pier Luigi; Suter, Ulrich W.; Gladiali, Serafino Helvetica Chimica Acta, 1981 , vol. 64, # 8 p. 2821 - 2829

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被引用次数: 5

摘要

Abstract Mixtures of the diastereomers of 2, 2, 3, 5, 6-pentamethylheptane were prepared in two ways, either starting with compounds of (3R)-configuration, or from compounds of (5R)- configuration. Comparison of the GC. and optical rotatory power of the fractions of these two mixtures permitted the unambiguous assignment of the absolute configuration and molar rotatory power to the various diastereomers ([M] math image=+ 119.1 for the (3R, 5R)-and ...