Oxidative alkoxylation of zinc phosphide in alcoholic solutions of copper (II) chloride

…, ZU Ibraimova, GS Polimbetova

文献索引：Dorfman; Ibraimova; Polimbetova Russian Journal of Physical Chemistry A, 2002 , vol. 76, # 1 p. 50 - 55

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被引用次数: 2

摘要

Résumé/Abstract Oxidative alkoxylation of Zn 3 P 2 with the formation of valuable phosphoric and phosphorous acid esters occurred at a high rate and with a high selectivity in alcoholic solutions of CuCl 2 under the action of oxygen at 30-60 C. Depending on the nature of the alcohol, two products were formed, namely, trialkyl phosphates (RO) 3 PO and dialkyl phosphites (RO) 2 HPO. Water favored the formation of dialkyl phosphates (RO) 2 ( ...