Preorganization of Achiral Molecules for Asymmetric Synthesis through Crystallization??Induced Immobilization in Homochiral Conformations

BO Patrick, JR Scheffer, C Scott

文献索引：Patrick, Brian O.; Scheffer, John R.; Scott, Carl Angewandte Chemie - International Edition, 2003 , vol. 42, # 32 p. 3775 - 3777

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被引用次数: 27

摘要

The work described in this article represents the latest installment from our laboratory in a long-term program aimed at developing new methods of asymmetric synthesis in organic photochemistry,[1] a relatively unexplored field that has recently attracted widespread attention and interest.[2] By way of introduction, consider the common situation of a conformationally mobile molecule that is achiral in solution as a result of rapid ...