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Canadian Journal of Chemistry

Nitration of p-tert-butyltoluene in acetic anhydride. 1, 2 and 1, 4 adducts

A Fischer, R Röderer

文献索引:Fischer,A.; Roederer,R. Canadian Journal of Chemistry, 1976 , vol. 54, p. 3978 - 3985

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被引用次数: 18

摘要

Nitration of p-tert-butyltoluene in acetic anhydride gives 5-tert-butyl-2-methyl-2-nitro-1, 2- dihydrophenyl acetate (43%), cis-and trans-1-tert-butyl-4-methyl-4-nitro-1, 4-dihydrophenyl acetate (16%) and 4-tert-butyl-2-nitrotoluene (41%). Reaction of either of the 1, 2 or 1, 4 ...