Catalytic Asymmetric Hydroboration/Amination and Alkylamination with Rhodium Complexes of 1, 1′??(2??Diarylphosphino??1??naphthyl) isoquinoline

E Fernandez, K Maeda, MW Hooper…

文献索引：Fernandez, Elena; Maeda, Kenji; Hooper, Mark W.; Brown, John M. Chemistry - A European Journal, 2000 , vol. 6, # 10 p. 1840 - 1846

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被引用次数: 102

摘要

Abstract Catecholboronate esters formed by asymmetric hydroboration of arylalkenes are not directly converted to amines by reaction with hydroxylamine-O-sulfonic acid. Prior conversion to a trialkylborane by reaction with ZnEt 2 or MeMgCl permits a subsequent ...