Tetrahedron

A new synthetic aspect of acetic nitronic anhydrides

M Miyashita, BZE Awen, A Yoshikoshi

文献索引：Miyashita, Masaaki; Awen, Bahlul Z. E.; Yoshikoshi, Akira Tetrahedron, 1990 , vol. 46, # 21 p. 7569 - 7586

被引用次数: 48

摘要

A facile and convenient synthesis of acetic nitronic anhydrides from aliphatic nitroalkenes and lithium ketone enolates and the efficient conversion of these anhydrides to 1, 4- diketones, alkylpyrroles, diketone monooximes, dihydro-1, 2-oxazines, pyrrolidines, 2- hydroxypyrrolidines, and 1-pyrrolines are recorded.

~61%

~38%

~83%

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