The electrical discharge reactions of CF2= CF2/Br2, CF2= CF2/BrCF2CF2Br, and BrCFgCFZBr were studied. In the CF1= CF2/Br2 system, the major products (63%) were identified as perfluoro-cup-dibromoalkanes. Minor amounts of perfluoroalkanes, 1- bromoperfluoroalkanes, and an essentially linear bromine-containing polymeric material were also present. From the CF2= CFp/BrCF2CF2Br system, similar products were ...
[Brel, Valery K.; Uvarov, Viktor I.; Zefirov, Nikolai S.; Stang, Peter J.; Caple, Ron Journal of Organic Chemistry, 1993 , vol. 58, # 24 p. 6922 - 6923]