Tetrahedron

Cinetique et mecanisme de la reaction de prototropie des composes propargyliques alleniques et propynyliques portant un heteroatome (colonne vb et vib)

G Pourcelot, P Cadiot, C Georgoulis

文献索引：Pourcelot, G.; Cadiot, P.; Georgoulis, C. Tetrahedron, 1982 , vol. 38, # 14 p. 2123 - 2128

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被引用次数: 6

摘要

A detailed kinetic study of the prototropic rearrangement of the system RMCH2 C CH⇌ RMCH C CH2⇌ RM C C CH3 where M= NR, O, Se is presented. using deuterated substrates the nature of the reactive intermediates and, in the case of M= S, the activation energy-reaction profile are established.