The Journal of Organic Chemistry

Chlorination of oximes. I. Reaction and mechanism of the chlorination of oximes in commercial chloroform and methylene chloride

YH Chiang

文献索引：Chiang,Y.H. Journal of Organic Chemistry, 1971 , vol. 36, p. 2146 - 2155

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被引用次数: 82

摘要

The chlorination of benzaldoximes in commercial chloroform and methylene chloride was undertaken. It was found that substituted oximes which possess electron-wtihdrawing groups gave bend chloride derivatives upon chlorination in methylene chloride and pure chloroform. On the other hand, benzhydroxamic chloride derivatives were obtained when chlorination was performed in commercial chloroform and methylene chloride containing ...