Reactivity, absorption and emission of dimethylgermylene photo-generated from dodecamethylcyclohexagermane

…, N Kanno, R Kato, M Kotani, S Yamauchi…

文献索引：Mochida, Kunio; Kanno, Naoko; Kato, Ryuji; Kotani, Masahiro; Yamauchi, Seigo; et al. Journal of Organometallic Chemistry, 1991 , vol. 415, # 2 p. 191 - 201

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被引用次数: 40

摘要

Abstract The UV photolysis of dodecamethylcyclohexagermane (1) in cyclohexane at room temperature proceeds readily with loss of dimethylgermylene species to give two of the lower homologs, decamethylcyclopentagermane (3). The photochemically generated dimethylgermylene species reacts with 2, 3-dimethylbuta-1, 3-diene or CCl 4 to give 1, 1, 3, 4-tetramethyl-1-germacyclopent-3-ene or trichloromethyldimethylchlorogermane, ...