Tetrahedron Letters

Highly regioselective hydroselenation of inactivated terminal alkynes using diselenide–Ph 2 P (O) H mixed systems under visible-light irradiation

Y Kobiki, S Kawaguchi, A Ogawa

文献索引：Kobiki, Yohsuke; Kawaguchi, Shin-Ichi; Ogawa, Akiya Tetrahedron Letters, 2013 , vol. 54, # 40 p. 5453 - 5456

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被引用次数: 4

摘要

Abstract Upon visible-light irradiation, we could achieve a highly regioselective hydroselenation of inactivated terminal alkynes to give 1-(organylseleno)-1-alkenes by using diselenide–Ph 2 P (O) H mixed systems. The photoinduced hydroselenation presented in this study is advantageous as it does not involve the handling of oxygen- sensitive and foul-smelling selenols.