Pinwheel motifs: formation of unusual homo-and hetero-nuclear aggregates via bridging thiolates

…, AJ Blake, PA Cooke, C Wilson, M Schröder

文献索引：Amoroso, Angelo J.; Chung, Simon S. M.; Spencer, Douglas J. E.; Danks, Jonathan P.; Glenny, Mark W.; Blake, Alexander J.; Cooke, Paul A.; Wilson, Claire; Schroeder, Martin Chemical Communications, 2003 , # 16 p. 2020 - 2021

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摘要

The homohexanuclear complexes [Ni2 {Ni (L1)} 4](BF4) 4· MeCN, 1,[Pd2 {Pd (L2)} 4](BF4) 4, 2, and the heteropentanuclear aggregate [Cu2 {Ni (L3)} 3](PF6) 2, 3, all adopt a 'pinwheel'type structural motif via thiolate bridging between square-planar Ni (II) or Pd (II) and between trigonal planar Cu (I) centres, respectively.