Reactions of tris (trimethylsilyl) silanecarboxylates with organolithium reagents

J Ohshita, E Nekoda, S Masaoka, M Ishikawa

文献索引：Ohshita, Joji; Nekoda, Eri; Masaoka, Shin; Ishikawa, Mitsuo Journal of Organometallic Chemistry, 1997 , vol. 544, # 1 p. 49 - 54

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被引用次数: 7

摘要

Chemical behavior of tris (trimethylsilyl) silamecarboxylates toward organolithium reagents was investigated. Treatment of triethylsilyl, triphenylsilyl, and methyl tris (trimethylsilyl) silanecarboxylate (1a-c) with organolithium reagents gave products which can be explained in terms of three types of reactions, the formation of lithium tris (trimethylsilyl) silanecarboxylate, abstraction of a trimethylsilyl group by the organolithium reagents, and ...