Chemical communications

Regioselective Heck arylation of unsaturated alcohols by palladium catalysis in ionic liquid

J Mo, L Xu, J Ruan, S Liu, J Xiao

文献索引：Mo, Jun; Xu, Lijin; Ruan, Jiwu; Liu, Shifang; Xiao, Jianliang Chemical Communications, 2006 , # 34 p. 3591 - 3593

全文：HTML全文

被引用次数: 33

摘要

In contrast to almost all of the known examples of Heck arylation of unsaturated alcohols, which yield predominately β-arylated products, arylation under the Pd-DPPP catalysis in ionic liquid leads preferentially to aryl substitution at the α carbon, providing an easy pathway to this valuable class of olefins.