Prop-2-ynyl-and propadienyl-lithium reagents. Regiocontrolled synthesis of allenic compounds

C Huynh, G Linstrumelle

文献索引：Huynh, Chanh; Linstrumelle, Gerard Journal of the Chemical Society, Chemical Communications, 1983 , # 20 p. 1133 - 1134

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被引用次数: 3

摘要

Prop-2-ynyl- and Propadienyl-lithium Reagents. Regiocontrolled Synthesis of Allenic Compounds ... Chanh Huynh and G6rard Linstrumelle ER 12 du CNRS, Laboratoire de Chimie, Ecole Normale Supe'rieure, 24, rue Lhomond, 75231 Paris Ce'dex 05, France ... Direct proof for the rearrangement of the prop-2-ynyl-lithium (2) into the propadienyl-lithium (4) is provided by the formation of the 1,3-disubstituted allenic compounds (7). ... The interest in prop-2-ynylmetals in organic ...