Epoxyethers. IX. Acid-catalyzed Rearrangements1

CL Stevens, SJ Dykstra

文献索引：Stevens; Dykstra Journal of the American Chemical Society, 1954 , vol. 76, p. 4402,4404

全文：HTML全文

被引用次数: 25

摘要

A wide variety of epoxyethers were cleanly rearranged to give a good yield of the corresponding methoxy ketones using magnesium bromide as a catalyst (cf. Table I). The structures of the new epoxyethers were proved by degradation reactions and the methoxy ketones were prepared independently or the structures proved by a second order Beckmann degradation of the corresponding oxime.