The Hydroxide??Promoted Catalytic Hydrodefluorination of Fluorocarbons by Ruthenium in Aqueous Media
MM Konnick, SM Bischof, RA Periana…
文献索引：Konnick, Michael M.; Bischof, Steven M.; Periana, Roy A.; Hashiguchi, Brian G. Advanced Synthesis and Catalysis, 2013 , vol. 355, # 4 p. 632 - 636
Abstract A ruthenium complex ligated by the non-innocent protic ligand 2, 6- imidizoylpyridine (IPI) in aqueous potassium hydroxide media is shown to be a suitable catalyst for the C [BOND] F bond activation and subsequent hydrodefluorination (and hydrogenolysis) of a model fluorocarbon. Furthermore, the conversion of C [BOND] F bonds was enhanced upon increasing the concentration of potassium hydroxide [KOH]. A simple, ...
