Tetrahedron letters

New method of in situ generation of nitrile oxides by MnO 2 oxidation of aldoximes

J Kiegiel, M Popławska, J Jóźwik, M Kosior, J Jurczak

文献索引：Kiegiel, Jaroslaw; Poplawska, Magdalena; Jozwik, Julita; Kosior, Malgorzata; Jurczak, Janusz Tetrahedron Letters, 1999 , vol. 40, # 30 p. 5605 - 5608

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被引用次数: 31

摘要

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Manganese(IV) oxide (MnO 2 ) was found to oxidize aldoximes to nitrile oxides. Nitrile oxides were trapped in situ with dipolarophiles to furnish 2-oxazolines. The best results were obtained with hydroximinoacetates as nitrile oxide precursors. ... Aldoximes when treated with ...