The Journal of Organic Chemistry

Stereochemistry. LXIX. Ring opening of aziridine phosphonates. Correlation of structure, nuclear magnetic resonance spectra, and reactivity

A Hassner, JE Galle

文献索引：Hassner,A.; Galle,J.E. Journal of Organic Chemistry, 1976 , vol. 41, p. 2273 - 2276

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被引用次数: 5

摘要

The ring opening of several dimethyl N-aziridinylphosphonates 3 with Clz and HC1 was studied. The reaction was found to be stereospecific and in most cases regiospecific. Conformational preferences in these compounds could be correlated with 1, 3 PH (PNCCH) coupling constants and with reactivity in ring opening.