Generation of perfluoro-and 1-chloropolyfluorobenzocycloalken-1-yl cations and their relative stability

IV Beregovaya, VM Karpov, TV Mezhenkova…

文献索引：Beregovaya; Karpov; Mezhenkova; Platonov; Chuikov Russian Journal of Organic Chemistry, 2012 , vol. 48, # 4 p. 523 - 528

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被引用次数: 3

摘要

Abstract Treatment of perfluorinated benzocyclobutene, indan, and tetralin with SbF 5-SO 2 Cl 2, as well as of their 1, 1-dichloro analogs with SbF 5, gave 1- chloropolyfluorobenzocycloalken-1-yl cations whose structure was studied by 19 F and 13 C NMR and confirmed by their transformations into perfluorinated ketones upon hydrolysis. Dissolution of perfluorinated benzocyclobutene, indan, and tetralin in excess SbF5 ...