The Journal of Organic Chemistry

Synthesis of hexahydrophosphindole oxides with oxygen functions at C-6

LD Quin, JE MacDiarmid

文献索引：Quin, Louis D.; MacDiarmid, Joan E. Journal of Organic Chemistry, 1981 , vol. 46, # 2 p. 461 - 464

全文：HTML全文

被引用次数: 4

摘要

When the McCormack cycloaddition is conducted at room temperature with CH3PC12, and the cycloadduct hydrolyzed with the pH controlled at neutrality or on the basic side, the phospholene oxides formed have the 3, 4-position for the double bond. This procedure led to the isolation of phospholene oxides 12 and 13 from dienes 9 and 10, respectively. The ketal derivative 12 is capable