… of the silicon. beta.-effect. Photoelectron and Penning ionization electron spectroscopic study of silylthiiranes and-oxiranes. Synthesis and chemistry of trans-2, 3-bis ( …
E Block, AJ Yencha, M Aslam…
文献索引:Block,E.; Yencha,A.J.; Aslam,M. Journal of the American Chemical Society, 1988 , vol. 110, p. 4748
Abstract: truns-2, 3-Bis (trimethylsilyl) thiirane (1) has been synthesized in two steps from trans-l, 2-bis (trimethylsilyI) ethene by addition of thiocyanogen followed by treatment of the adduct with sodium borohydride or lithium aluminum hydride. In the latter case minor products include mem-1, 2-bis (trimethylsilyl) ethane-l, 2-dithiol and 1, 2-bis (trimethylsilyl) ethanethiol.