Infrared and Raman spectra, conformational stability, ab initio calculations, and vibrational assignments for cyclopropylchlorosilane

…, S Shen, M Dakkouri, A Grunvogel-Hurst…

文献索引：Gounev; Weston, Jeffery W.; Shen, Shiyu; Dakkouri; Grunvogel-Hurst; Durig Journal of Physical Chemistry A, 1997 , vol. 101, # 46 p. 8614 - 8624

全文：HTML全文

被引用次数: 13

摘要

The infrared (3300-30 cm-1) spectra of gaseous and solid cyclopropylchlorosilane, c- C3H5SiH2Cl, have been recorded. Additionally, the Raman spectra (3200-30 cm-1) of the liquid and solid have been recorded and quantitative depolarization values obtained. Both the cis and gauche conformers have been identified in the fluid phases but only the gauche conformer remains in the solid. Variable-temperature (-55 to-100° C) studies of the ...