Tetrahedron letters

Triethylborane induced perfluoroalkylation of silyl enol ethers or germyl enol ethers with perfluoroalkyl iodides

K Miura, M Taniguchi, K Nozaki, K Oshima, K Utimoto

文献索引：Miura, Katsukiyo; Taniguchi, Masahiko; Nozaki, Kyoko; Oshima, Koichiro; Utimoto, Kiitiro Tetrahedron Letters, 1990 , vol. 31, # 44 p. 6391 - 6394

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被引用次数: 76

摘要

Abstract Reaction of perfluoroalkyl iodides with silyl enol ethers mediated by Et 3 B in the presence of a base provides perfluoroalkylated silyl enol ethers. Meanwhile, treatment of germyl enol ethers with perfluoroalkyl iodides affords β-perfluoroalkyl ketones in good yields.