Tetrahedron: Asymmetry

Asymmetric Suzuki cross-coupling reaction: chirality reversal depending on the palladium–chiral phosphine ratio

AS Castanet, F Colobert, PE Broutin, M Obringer

文献索引：Castanet, Anne-Sophie; Colobert, Francoise; Broutin, Pierre-Emmanuel; Obringer, Michel Tetrahedron Asymmetry, 2002 , vol. 13, # 6 p. 659 - 665

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被引用次数: 110

摘要

Suzuki cross-coupling reaction with sterically hindered arylboronic acids is reported. Good yields are obtained by using DME and cesium fluoride in the presence of Pd (OAc) 2 and triphenylphosphine. The catalytic asymmetric reaction between 2-methoxy-1- ...