STUDY OF THE ALKALINE CLEAVAGE OF THE P [sbnd] C BOND IN PHOSPHINE OXIDES AND DERIVATIVES OF TRICHLOROMETHANEPHOSPHONATE

G Aksnes, R Gierstae, EA Wulvik

文献索引：Aksnes, Gunnar; Gierstae, Roald; Wulvik, Erik A. Phosphorus and Sulfur and the Related Elements, 1988 , vol. 39, p. 141 - 152

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被引用次数: 7

摘要

Abstract A study of alkaline decomposition of several aromatic phosphine oxides containing p-and o-nitrobenzyl, and trichloromethyl as leaving groups, is reported. The property of the trichloromethyl group as leaving group, and the CCl− 3-group's further decomposition in the hydrolysis of diethyl and disodium trichloromethanephosphonates, have also been investigated.