Journal of the American Chemical Society

True metal-catalyzed hydroboration with titanium

X He, JF Hartwig

文献索引：He, Xiaoming; Hartwig, John F. Journal of the American Chemical Society, 1996 , vol. 118, # 7 p. 1696 - 1702

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被引用次数: 130

摘要

Dicarbonyltitanocene is an efficient and highly selective catalyst for alkyne hydroborations by catecholborane and dimethyltitanocene is an efficient and highly selective catalyst for alkene hydroborations. These results contrast the hydroboration chemistry with other early transition metal complexes that simply lead to decomposition of catecholborane to form diborane and parallel the hydroboration chemistry of permethylcyclopentadienyl ...