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Tetrahedron

Interconversion of benzofurazandione monoximes

AS Angeloni, D Dal Monte, E Sandri, G Scapini

文献索引:Angeloni,A.S. et al. Tetrahedron, 1974 , vol. 30, p. 3849 - 3857

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被引用次数: 5

摘要

The preparation of 5-hydroxy-4-nitroso-and 7-hydroxy-4-nitrosobenzofurazan as well as of their 6-chloro and methyl derivatives is described and the oxime structure of these compounds is established. NMR spectra of benzofurazan-4, 5-dione-4-monoxime and benzofurazan-4, 7-dione-4-monoxime show evidence for an interconversion, in solution, of two monoximes, the 4, 5-and 4, 7-derivative prevailing in organic solvents and aqueous ...