Australian Journal of Chemistry

Radical reactions of p-Nitrobenzylidene dichloride with lithium 2-nitropropan-2-ide. Consecutive SRN1 and ERC1 reactions

DJ Freeman, RK Norris

文献索引：Freeman,D.J.; Norris,R.K. Australian Journal of Chemistry, 1976 , vol. 29, p. 2631 - 2642

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被引用次数: 10

摘要

Abstract The reaction of p-nitrobenzylidene dichloride with the lithium salt of 2-nitropropane gives initially the monosubstituted compound, p-NO 2 C 6 H 4 CH (Cl) CMe 2 NO 2, by a radical-anion radical chain, S RN 1 process. This compound then undergoes a radical-anion radical chain elimination reaction giving the styrene, p-NO 2 C 6 H 4 CH= CMe 2, and the dimer of 2-nitropropane, Me 2 C (NO 2) CMe 2 NO 2. This latter reaction, which is ...