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Carbohydrate research

Syntheses of 1-(5-deoxy-β-d-arabino-hexofuranosyl) cytosine

M Iwakawa, OR Martin, WA Szarek

文献索引：Iwakawa, Masaharu; Martin, Olivier R.; Szarek, Walter A. Carbohydrate Research, 1983 , vol. 121, p. 99 - 108

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被引用次数: 5

摘要

Abstract 1-(5-Deoxy-β-d-arabino-hexofuranosyl) cytosine (4′-homoara-C)(11), a higher homolog of the antileukemic agent ara-C (1-β-d-arabinofuranosylcytosine), was prepared by two independent routes. The first one involved the inversion of configuration at C-2′ of the d-ribo epimer (1-(5-deoxy-β-d-ribo-hexofuranosyl) cytosine, 4′-homocytidine) by the diphenylcarbonate technique; the 5-deoxy-d-ribo-hexofuranosyl moiety of 4′- ...

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