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Chitosan based heterogeneous catalyses: chitosan-grafted-poly (4-vinylpyridne) as an efficient catalyst for michael additions and alkylpyridazinyl carbonitrile …

KD Khalil, HM Al-Matar

文献索引:Khalil, Khaled D.; Al-Matar, Hamad M. Molecules, 2013 , vol. 18, # 5 p. 5288 - 5305

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被引用次数: 8

摘要

Abstract: Chitosan-grafted-poly (4-vinylpyridine)(Cs-PVP) copolymers could be synthesized under heterogeneous conditions in presence of a potassium persulfate and sodium sulfite redox system. The synthesized graft copolymer could be utilized effectively, in the form of beads, as an efficient catalyst for Michael additions of active methylenes to functionally substituted alkenes. Moreover, methyl moiety oxidation in methyl pyridazinyl carbonitriles ...