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Macromolecules

Charge transfer complexes of discotic liquid crystals: A flexible route to a wide variety of mesophases

PHJ Kouwer, WF Jager, WJ Mijs, SJ Picken

文献索引:Kouwer, Paul H.J.; Jager, Wolter F.; Mijs, Wim J.; Picken, Stephen J. Macromolecules, 2002 , vol. 35, # 11 p. 4322 - 4329

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被引用次数: 47

摘要

We have prepared a new discotic nematogen, bearing one functional tail and five methoxy substituents. The corresponding side chain polymers, prepared via a polymer analogous esterification reaction, exhibited ND phases from 50° C until degradation above 200° C. Addition of equimolar amounts of various trinitrofluorenone-based acceptors to the mesogen resulted in the formation of charge transfer complexes with a variety in liquid crystalline ...