Journal of the American Chemical Society

Novel route to bicyclo [3.3. 1] non-1-ene. Supporting evidence for Wiseman's postulate

M Kim, JD White

文献索引：Kim,M.; White,J.D. Journal of the American Chemical Society, 1975 , vol. 97, # 2 p. 451 - 453

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被引用次数: 8

摘要

The failure of Bredt's rule, as formulated in the quantitative expression (" S number") of Fawcett, to account for differences in strain between isomeric bridgehead olefins, eg, 1 and 2, represents a serious shortcoming of this numerical approach.'In contrast, the proposal by Wiseman2 that the strain in bridgehead alkenes is closely related to the strain of the corresponding trans cycloalkene accounts well for the properties of known bridgehead ...