Transition metal promoted alkylations of unsaturated alcohols: the selective methylation of homopropargyl alcohols via titanium tetrachloride-trimethylaluminum

…, DW Moore, FW Schultz, DW Thompson

文献索引：Ewing, James C.; Ferguson, Gregory S.; Moore, Douglas W.; Schultz, Frederick W.; Thompson, David W. Journal of Organic Chemistry, 1985 , vol. 50, # 12 p. 2124 - 2128

全文：HTML全文

被引用次数: 13

摘要

The reactions of homopropargyl alcohols with titanium tetrachloride-trimethylaluminum in methylene chloride under mild conditions selectively yield after hydrolysis alkenols of the type HOCH (R) CH, CH= C (R') CH,, R= H, Me, and Et and R'= H, Me, Et, n-Pr, i-Pr, nC, H9, n- C5HIl, and Ph.