The Preparation and Polymerization of Four Isomeric Dimethylstyrenes1, 2

…, JH Saunders, CG Overberger

文献索引：Marvel; Saunders; Overberger Journal of the American Chemical Society, 1946 , vol. 68, p. 1085,1086

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被引用次数: 30

摘要

Summary 1.@-Chloroethyltrichlorosilane and 8-chloron-propyltrichlorosilane with aqueous alkali give ethylene and propylene, respectively. The extremely rapid reaction of beta C-Cl bonds with dilute alkali is not a hydrolysis, but a@-elimination, similar in type to the dehydrohalogenation of alkyl halides. It involves tetracovalent silicon instead of a combined hydrogen atom. 2. Reaction of@-chloroethyltrichlorosilane with methylmagnesium ...