Palladium??Catalyzed Reduction of Carboxylic Acids to Aldehydes with Hydrosilanes in the Presence of Pivalic Anhydride

T Fujihara, C Cong, J Terao…

文献索引：Fujihara, Tetsuaki; Cong, Cong; Terao, Jun; Tsuji, Yasushi Advanced Synthesis and Catalysis, 2013 , vol. 355, # 17 p. 3420 - 3424

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被引用次数: 4

摘要

Abstract: A palladium catalyst system that allows the reduction of carboxylic acids to the corresponding aldehydes with hydrosilanes as reducing agent and pivalic anhydride as an indispensable reagent has been developed. A simple mixture of commercially available bis ( dibenzylideneacetone) palladium (0)[PdACHTUNGTRENNUNG (dba) 2], tri (para-tolyl) phosphane and methylphenylsilane realized the reduction of various aliphatic carboxylic ...