The Journal of Organic Chemistry

Solvolysis of. alpha.-arylvinyl ethyl phosphates in aqueous and methanolic solutions: intramolecular participation by the [(ethyloxy) phosphoryl] oxy group

M Novak, KR Roy

文献索引：Novak, Michael; Roy, Kalpana R. Journal of Organic Chemistry, 1984 , vol. 49, # 24 p. 4584 - 4590

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被引用次数: 2

摘要

The a-arylvinyl ethyl phosphates 2a-c were synthesized and their solvolysis reactions were studied in acidic aqueous solution and methanol. In aqueous solution both the anionic and neutral diesters are subject to acid-catalyzed hydrolysis. Solvent deuterium isotope effects,