Metathesis of unsaturated fatty acids: Synthesis of long-chain unsaturated-α, ω-dicarboxylic acids

HL Ngo, K Jones, TA Foglia

文献索引：Ngo, Helen L.; Jones, Kerby; Foglia, Thomas A. JAOCS, Journal of the American Oil Chemists' Society, 2006 , vol. 83, # 7 p. 629 - 634

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被引用次数: 80

摘要

Abstract The self-metathesis of readily available monounsaturated FA has the potential of being an important pathway for the synthesis of symmetrical long-chain unsaturated-α, ω- dicarboxylic acids (C 18− C 26). Previous studies on the self-metathesis of monounsaturated FA esters using ruthenium catalysts in solution, however, suffered from low conversions as a result of the thermodynamic control of the reaction. We have found that the second- ...