Journal of the American Chemical Society

Electron-transfer reactions in organic chemistry. 4. A mechanistic study of the oxidation of p-methoxytoluene by 12-tungstocobalt (III) ate ion

L Eberson

文献索引：Eberson, Lennart Journal of the American Chemical Society, 1983 , vol. 105, # 10 p. 3192 - 3199

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被引用次数: 132

摘要

Abstract: A kinetic study of the oxidation of p-methoxytoluene by the heteropolyion 12- tungstwobalt (III) ate (Co"'W120405-) in acetic acid/water with an acetate salt present has been performed. The rate of disappearance of the cobalt species is first order in [p- methoxytoluene] and [AcO-](at [AcO-] C 0.25 M) and inverse first order in the final concentration of CO~~ W,, O,~. The reaction is strongly affected by the nature of the cation ...