Silicon-Fluorine Chemistry. IV. The Reaction of Silicon Difluoride with Aromatic Compounds

PL Timms, DD Stump, RA Kent…

文献索引：Timms,P.L. et al. Journal of the American Chemical Society, 1966 , vol. 88, # 5 p. 940 - 942

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被引用次数: 50

摘要

Abstract: A study has been made of the reactions of silicon difluoride with some fluorinated and nonfluorinated aromatic compounds at low temperatures. Perfluorobenzene gives the substitution products C6F6SiFa and C6F4-(SiF&. Benzene and toluene give a group of compounds of type ArH (SiF2),, where n= 2 to 8. The compounds CeHeSi3F6 and C6HsCHaSirF6 are 1, Ccyclohexadiene derivatives with-SiF2-SiFz-SiFz-bridges across ...