Advanced Synthesis & Catalysis

The N??Alkylation of Sulfonamides with Alcohols in Water Catalyzed by the Water??Soluble Iridium Complex {Cp* Ir [6, 6′??(OH) 2bpy](H2O)}[OTf] 2

P Qu, C Sun, J Ma, F Li

文献索引：Qu, Panpan; Sun, Chunlou; Ma, Juan; Li, Feng Advanced Synthesis and Catalysis, 2014 , vol. 356, # 2-3 p. 447 - 459

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被引用次数: 37

摘要

Abstract: The water-soluble iridium complex {Cp* Ir-ACHTUNGTRENNUNG [6, 6'-(OH) 2bpy] ACHTUNGTRENNUNG (H2O)} ACHTUNGTRENNUNG [OTf] 2 (Cp*= η5- pentamethylcyclopentadienyl, bpy= 2, 2'-bipyridine) was found to be a general and highly efficient catalyst for the N-alkylation of the poor nucleophilic sulfonamides with alcohols as alkylating agents in water. The presence of OH units in the bpy ligand is crucially ...