Organic Process Research & Development

Synthesis of hexanitrostilbene (HNS) using a Kenics static mixer

AJ Bellamy

文献索引：Bellamy, Anthony J. Organic Process Research and Development, 2010 , vol. 14, # 3 p. 632 - 639

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被引用次数: 7

摘要

Previous work on a Shipp− Kaplan type synthesis of hexanitrostilbene (HNS) using a Kenics static mixer (ref 1, from Chemineer Ltd., Cranmer Road, West Meadows, Derby DE21 6XT, UK; www. chemineer. com) has been extended by using a larger mixer (9.5 mm vs 4.75 mm OD), enabling the scale to be increased from 2.5 g to 25 g of trinitrotoluene (TNT) for the same mixing time (< 4 min). Various conditions for the after-reaction period (2 h) have ...