Chemistry Letters

Cobalt-Catalyzed Photochemical Carbonylation of Allylic Amines.

S Mori, H Matsuyoshi, K Kudo, N Sugita

文献索引：Mori, Sadayuki; Matsuyoshi, Hiroaki; Kudo, Kiyoshi; Sugita, Nobuyuki Chemistry Letters, 1991 , # 8 p. 1397 - 1400

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被引用次数: 4

摘要

Allylic amines are carbonylated at room temperature in the presence of cobalt catalysts under UV irradiation. With allylamine, 2-pyrrolidone, N, N′-diallylurea, and N-allyl-3- butenamide were obtained. The photochemical cleavage of C–N bond of amines coordinated to cobalt metals was suggested.