Micellar effects on the reaction of (arylsulfonyl) alkyl arenesulfonates with hydroxide ion. 1. Microenvironmental and substituent effects in the Stern layer of cationic …

GB Van de Langkruis…

文献索引：van de Langkruis, Gerard B.; Engberts, Jan B. F. N. Journal of Organic Chemistry, 1984 , vol. 49, # 22 p. 4152 - 4157

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被引用次数: 13

摘要

The reaction of the sulfonates p-XC6H, S02CH (R) OS02C6H~ Yp la-g with hydroxide ion (involving nucleophilic attack at sulfonate sulfur) is accelerated (7-25 times) in the presence of CTAB micelles (32.1" C). The kinetic data are analyzed in detail by using the