前往化源商城

举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

The Journal Of Organic Chemistry

The Conversion of Phenols to Thiophenols via Dialkylthiocarbamates1

MS Newman, HA Karnes

文献索引：Newman,M.S.; Karnes,H.A. Journal of Organic Chemistry, 1966 , vol. 31, p. 3980 - 3984

全文：HTML全文

被引用次数: 351

摘要

A number of phenols and hydroxyheterocyclic compounds have been converted to the corresponding thiol compounds by the route, phenol to 0-aryl dialkylthiocarbamate to S-aryl dialkylthiocarbamate to thiophenol. Methods for accomplishing each step in high yield are described. Since the thiol compounds formed are readily desulfurized by heating with Raney nickel, a useful way of replacing aromatic hydroxyl groups by hydrogen is at hand.

吗啉结构式

N-甲基吗啉结构式

4-tert-butylphenyl chlorothionoformate结构式

4-tert-butylphe...

~%

morpholin-4-yl-(4-tert-butylphenoxy)methanethione结构式

morpholin-4-yl-...

查看详情

N,N-Dimethyl-thiocarbamidsaeure-O-(4-dimethylamino-phenylester)结构式

N,N-Dimethyl-th...

~%

Carbamicacid, dimethylthio-, S-[p-(dimethylamino)phenyl] ester (8CI)结构式

Carbamicacid, d...

查看详情

N,N-dimethyl-1-(4-tert-butylphenoxy)methanethioamide结构式

N,N-dimethyl-1-...

~%

Carbamothioic acid,dimethyl-, S-[4-(1,1-dimethylethyl)phenyl] ester (9CI)结构式

Carbamothioic a...

查看详情

sodium p-tert-butylphenolate结构式

sodium p-tert-b...

~%

Carbamothioic acid,dimethyl-, S-[4-(1,1-dimethylethyl)phenyl] ester (9CI)结构式

Carbamothioic a...

查看详情

尼泊金甲酯钠结构式

尼泊金甲酯钠

~%

Benzoic acid,4-[[(dimethylamino)carbonyl]thio]结构式

Benzoic acid,4-...

查看详情

2,6-di-tert-butyl-4-methylphenol, sodium salt结构式

2,6-di-tert-but...

二甲氨基一硫代甲酰氯结构式

二甲氨基一硫代甲酰氯

~%

N,N-dimethyl-1-(4-methyl-2,6-ditert-butyl-phenoxy)methanethioamide结构式

N,N-dimethyl-1-...

查看详情

sodium 2-methoxyphenolate结构式

sodium 2-methox...

二甲氨基一硫代甲酰氯结构式

二甲氨基一硫代甲酰氯

~%

Carbamothioic acid,N,N-dimethyl-, O-(2-methoxyphenyl) ester结构式

Carbamothioic a...

查看详情

N-methyl-1-(4-nitrophenoxy)-N-phenyl-methanethioamide结构式

N-methyl-1-(4-n...

~%

Carbanilic acid,N-methylthio-, S-(p-nitrophenyl) ester (8CI)结构式

Carbanilic acid...

查看详情

Carbonochloridothioicacid, O-(4-nitrophenyl) ester结构式

Carbonochlorido...

~%

Carbanilic acid,N-methylthio-, S-(p-nitrophenyl) ester (8CI)结构式

Carbanilic acid...

查看详情

N-甲基苯胺结构式

~%

Carbanilic acid,N-methylthio-, S-(p-nitrophenyl) ester (8CI)结构式

Carbanilic acid...

查看详情

Carbonochloridothioicacid, O-(4-nitrophenyl) ester结构式

Carbonochlorido...

N-甲基苯胺结构式

~%

N-methyl-1-(4-nitrophenoxy)-N-phenyl-methanethioamide结构式

N-methyl-1-(4-n...

查看详情

2-萘酚钠结构式

二甲氨基一硫代甲酰氯结构式

二甲氨基一硫代甲酰氯

~%

Carbamothioicacid, N,N-dimethyl-, O-2-naphthalenyl ester结构式

Carbamothioicac...

查看详情

N-[4-(dimethylthiocarbamoyloxy)phenyl]acetamide结构式

N-[4-(dimethylt...

~%

N-[4-(dimethylcarbamoylsulfanyl)phenyl]acetamide结构式

N-[4-(dimethylc...

查看详情

sodium 4-acetylaminophenolate结构式

sodium 4-acetyl...

~%

N-[4-(dimethylcarbamoylsulfanyl)phenyl]acetamide结构式

N-[4-(dimethylc...

查看详情

Carbonochloridothioicacid, O-(4-nitrophenyl) ester结构式

Carbonochlorido...

N-甲基-4-硝基苯胺结构式

N-甲基-4-硝基苯胺

~%

N-methyl-1-(4-nitrophenoxy)-N-(4-nitrophenyl)methanethioamide结构式

N-methyl-1-(4-n...

查看详情

2,4,5-三氯苯酚钠结构式

2,4,5-三氯苯酚钠

二甲氨基一硫代甲酰氯结构式

二甲氨基一硫代甲酰氯

~%

Carbamothioic acid,dimethyl-, O-(2,4,5-trichlorophenyl) ester (9CI)结构式

Carbamothioic a...

查看详情

Carbamothioic acid,dimethyl-, O-(2,4,5-trichlorophenyl) ester (9CI)结构式

Carbamothioic a...

~%

Carbamothioic acid,dimethyl-, S-(2,4,5-trichlorophenyl) ester (9CI)结构式

Carbamothioic a...

查看详情

2,4,5-三氯苯酚钠结构式

2,4,5-三氯苯酚钠

~%

Carbamothioic acid,dimethyl-, S-(2,4,5-trichlorophenyl) ester (9CI)结构式

Carbamothioic a...

查看详情

sodium 4-acetylaminophenolate结构式

sodium 4-acetyl...

二甲氨基一硫代甲酰氯结构式

二甲氨基一硫代甲酰氯

~%

N-[4-(dimethylthiocarbamoyloxy)phenyl]acetamide结构式

N-[4-(dimethylt...

查看详情

N-methyl-1-(4-nitrophenoxy)-N-(4-nitrophenyl)methanethioamide结构式

N-methyl-1-(4-n...

~%

N-methyl-N-(4-nitrophenyl)-1-(4-nitrophenyl)sulfanyl-formamide结构式

N-methyl-N-(4-n...

查看详情

N-甲基-4-硝基苯胺结构式

N-甲基-4-硝基苯胺

~%

N-methyl-N-(4-nitrophenyl)-1-(4-nitrophenyl)sulfanyl-formamide结构式

N-methyl-N-(4-n...

查看详情

sodium 4-methoxyphenyl oxide结构式

sodium 4-methox...

~%

Carbamothioic acid,N,N-dimethyl-, S-(4-methoxyphenyl) ester结构式

Carbamothioic a...

查看详情

disodium salt of hydroquinone结构式

disodium salt o...

二甲氨基一硫代甲酰氯结构式

二甲氨基一硫代甲酰氯

~%

Carbamothioicacid, dimethyl-, O,O'-1,4-phenylene ester (9CI)结构式

Carbamothioicac...

查看详情

sodium 4-methoxyphenyl oxide结构式

sodium 4-methox...

二甲氨基一硫代甲酰氯结构式

二甲氨基一硫代甲酰氯

~%

Carbamothioic acid,N,N-dimethyl-, O-(4-methoxyphenyl) ester结构式

Carbamothioic a...

查看详情

sodium salt of estrone结构式

sodium salt of ...

二甲氨基一硫代甲酰氯结构式

二甲氨基一硫代甲酰氯

~%

N,N-dimethyl-1-[(13-methyl-17-oxo-7,8,9,11,12,14,15,16-octahydro-6H-cyclopenta[a]phenanthren-3-yl)oxy]methanethioamide结构式

N,N-dimethyl-1-...

查看详情

sodium 2-methoxyphenolate结构式

sodium 2-methox...

~%

1-(2-methoxyphenyl)sulfanyl-N,N-dimethyl-formamide结构式

1-(2-methoxyphe...

查看详情

Na(OC6H4-p-NH2)结构式

Na(OC6H4-p-NH2)

二甲氨基一硫代甲酰氯结构式

二甲氨基一硫代甲酰氯

~%

1-(4-aminophenoxy)-N,N-dimethyl-methanethioamide结构式

1-(4-aminopheno...

查看详情

2-Hydroxyacetophenone sodium salt结构式

2-Hydroxyacetop...

二甲氨基一硫代甲酰氯结构式

二甲氨基一硫代甲酰氯

~%

Carbamothioic acid,dimethyl-, O-(2-acetylphenyl) ester (9CI)结构式

Carbamothioic a...

查看详情