Journal of the American Chemical Society

Novel transformation of primary, secondary, and tertiary amines to organoselenides with ruthenium catalyst

S Murahashi, T Yano

文献索引：Murahashi, Shun-Ichi; Yano, Tsuneo Journal of the American Chemical Society, 1980 , vol. 102, # 7 p. 2456 - 2458

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被引用次数: 38

摘要

lJpc= 20.5 Hz, PCH2), 28.8 ppm (s,(CH3) 3). I3C NMR (IH gated decoupled,~ JCH only): 126.0 Hz (C,), 178.8 (Cp), 130.4 (PCH2),, 128.0 ((CH3) 3)., The preparation of [Fp'= CHC (CH3) 3JBF4'(7) from 6 represents the first instance of the preparation of a nonheteroatom- substituted alkylidene complex from an alkenyl precursor.'The infrared spectrum (mull) of 7 did not display the low-frequency CH stretching mode (-2500 cm-I) found in ...