Reaction of 1, 3-dithiane anions with nitriles: generation of primary aminoketene thioacetals
PCB Page, MB van Niel, PH Williams
文献索引：Page, Philip C. Bulman; Niel, Monique B. van; Williams, P. Howard Journal of the Chemical Society, Chemical Communications, 1985 , # 11 p. 742 - 743
The anions derived from 1,3-dithiane and 2-trimethylsilyl-I ,3-dithiane react with simple nitriles to provide primary aminoketene thioacetals. ... The chemistry of the anions derived from 173-dithiane and 1,3-0xathiane has been extensively studied and reviewed ,1 particularly with regard to the use of these materials as acyl anion equivalents. However although the corresponding 2-trimethylsilyl derivatives have found application in ketene thioacetal generation2 they ...
