Tetrahedron letters

Organoaluminum-catalyzed new alkylation of tert-alkyl fluorides: Synthetic utility of Al F interaction

T Ooi, D Uraguchi, N Kagashima, K Maruoka

文献索引：Ooi, Takashi; Uraguchi, Daisuke; Kagoshima, Naoko; Maruoka, Keiji Tetrahedron Letters, 1997 , vol. 38, # 32 p. 5679 - 5682

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被引用次数: 43

摘要

tert-Alkyl fluorides have been revisited as promising alkylation agents based on the activation of fluorine as a leaving group by organoaluminums through the eminent Al F interaction. Trialkylaluminums were found to be excellent catalysts as well as alkylation agents.