Reductions with diphenylhydroxymethyl radicals. Synthesis of dianthrylethanes and dianthrylethylenes

HD Becker, D Sanchez, A Arvidsson

文献索引：Becker,H.-D. et al. Journal of Organic Chemistry, 1979 , vol. 44, # 24 p. 4247 - 4251

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被引用次数: 14

摘要

The reductive dimerization of 10-methyleneanthrone by diphenylhydroxymethyl radicals, generated by thermal dissociation of benzpinacol, gives 1, 2-bis (10-hydroxy-9-anthry1) ethane. Its utilization in the synthesis of an-thronylethyl-substituted anthracenes, dianthrylethanes, and dianthrylethylenes is described. The compound reported in the literature to be the cis isomer of 1, 2-bis (9-anthryl) ethylene apparently is 9- ...