Journal of the American Chemical Society

NMR study of the PC (OH)-P to PCOP rearrangement: Tetraethyl 1-hydroxyalkylidenediphosphonates

SJ Fitch, K Moedritzer

文献索引：Fitch,S.J.; Moedritzer,K. Journal of the American Chemical Society, 1962 , vol. 84, p. 1876 - 1879

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被引用次数: 88

摘要

RC (OH)[P (O)(OR') zIz (1) prepare diphosphonates by the reported methods led to the formation of isomeric compounds containing two chemically different kinds of phosphorus atoms. This finding was interpreted as meaning that the initially formed diphosphonates had rearranged to the isomeric phosphates. Sub-